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Retatrutide (LY3437943)

Identification

Property Value
Molecular Formula C₂₂₃H₃₄₃N₄₇O₆₈
Molecular Weight ~4,845.5 Da
Amino Acid Count 39
Appearance White to off-white lyophilized powder
Solubility Soluble in aqueous buffers; may require pH adjustment for complete dissolution
Receptor Targets GIPR / GLP-1R / GCGR (triple agonist)

Structural & Pharmacological Profile

Retatrutide is an investigational triple-hormone-receptor agonist designed to activate the glucose-dependent insulinotropic polypeptide receptor (GIPR), glucagon-like peptide-1 receptor (GLP-1R), and glucagon receptor (GCGR). The peptide features a 39-amino acid backbone with structural modifications enabling balanced activity across all three receptors and an extended pharmacokinetic profile via a C20 fatty diacid-albumin binding mechanism.

Key Structural Features

Feature Detail
Peptide Backbone 39-amino acid single-chain peptide with targeted sequence modifications for triple receptor agonism
Fatty Acid Moiety C20 eicosanedioic acid
Linker Chemistry gamma-Glu-2xOEG spacer to Lys residue
Glucagon Activity Amino acid substitutions in the glucagon homology region provide balanced GCGR agonism without inducing hyperglycemia
Half-Life ~6 days in preclinical models

Comparator Analysis

Parameter Semaglutide Tirzepatide Retatrutide
Receptor Target GLP-1R (selective) GIPR / GLP-1R (dual) GIPR / GLP-1R / GCGR (triple)
Molecular Weight ~4,113.6 Da ~4,813.5 Da ~4,845.5 Da
Amino Acid Count 31 39 39
Clinical BW Reduction ~14.9% (68 wk) ~22.5% (72 wk) ~24.2% (Phase 2, 48 wk)
Half-Life ~7 days ~5 days ~6 days
Synthesis Complexity High Very High Complex
GCGR Activity None None Yes
Fatty Acid Linker C18 fatty diacid C20 fatty diacid C20 fatty diacid

Clinical data cited from published trial results in peer-reviewed literature. Phase 2 data for retatrutide is from a 48-week dose-ranging study; Phase 3 outcomes may differ.

Research Applications

Research Domain Description
Body Weight & Energy Expenditure GCGR activation increases energy expenditure and lipid oxidation, complementing the anorectic effects of GLP-1R and GIPR agonism
Glucose Homeostasis Balanced triple agonism provides GIPR-mediated insulin secretion, GLP-1R-mediated glucose-dependent insulin potentiation, and GCGR-mediated hepatic glucose output modulation
Hepatic Lipid Metabolism GCGR component increases hepatic fatty acid oxidation; reduced liver fat content observed in Phase 2 imaging substudies
Cardiovascular & Renal Under investigation in outcome trials; early data suggest blood pressure and lipid improvements beyond weight loss alone
NASH / MASLD Triple agonism may address multiple pathogenic drivers simultaneously: steatosis, inflammation, and fibrogenesis
Combination Potential Investigated with amylin analogs (e.g., cagrilintide) for additive metabolic effects

Quality Specifications

Parameter Specification Method
Purity (HPLC) ≥99.0% RP-HPLC, 214 nm
Mass Identity MW ±1.0 Da ESI-MS
Water Content ≤5.0% Karl Fischer titration
Peptide Content ≥80.0% Amino acid analysis
Counterion Acetate (≤1.0% TFA) Ion chromatography
Endotoxin ≤1.0 EU/mg LAL kinetic chromogenic
Residual Solvents ≤ ICH Q3C limits Headspace GC
pH (1 mg/mL) 4.5–7.0 Potentiometric

Available Configurations

Format Size Vials per Kit
Standard Research Kit 5 mg × 10 vials 10
Extended Research Kit 10 mg × 10 vials 10
Custom Configuration Per project Per scope

Storage & Stability

Condition Requirement
Short-term Storage 2–8°C, lyophilized
Long-term Storage −20°C to −80°C, desiccated
Reconstituted 24 h at 2–8°C; −20°C for freezer aliquots
Shipping Cold chain recommended; ambient ≤7 days

Documentation

  • COA per batch: chromatographic purity, MS identity, quantitative analysis
  • MSDS provided with each shipment

Special Notes

  • FOR LABORATORY RESEARCH USE ONLY.
  • Retatrutide is an investigational compound. The synthesis complexity, while slightly less than tirzepatide due to more favorable solubility and purification characteristics, still requires advanced solid-phase peptide synthesis expertise and rigorous QC.
  • Triple receptor agonism research should account for potential crosstalk between GIPR, GLP-1R, and GCGR signaling cascades when designing dose-response experiments.
  • The GCGR component distinguishes retatrutide from dual agonists; researchers studying metabolic endpoints should consider including glucagon and FGF21 measurements in their protocols.

Key Research References

Reference PMID Key Finding
Jastreboff AM et al. "Triple-hormone-receptor agonist retatrutide for obesity — a phase 2 trial." N Engl J Med. 2023;389(6):514–526. 37366315 Phase 2 trial: retatrutide produced up to 24.2% body weight reduction at 48 weeks; dose-dependent improvements in liver fat, lipids, and glycemic control
Coskun T et al. "LY3298176, a novel dual GIP and GLP-1 receptor agonist for the treatment of type 2 diabetes mellitus: From discovery to clinical proof of concept." Mol Metab. 2018;18:3–14. 30473097 While primarily describing tirzepatide, this foundational paper also characterizes the GIP/GLP-1/GCGR triple agonism framework that enabled retatrutide's design; details C20 fatty acid linker and balanced receptor activity engineering

Stability & Storage

Condition Degradation Profile
Lyophilized Storage Standard GLP-1 receptor agonist family stability profile; no special handling beyond desiccated, temperature-controlled storage. 24 months at 2–8°C, 36 months at −20°C
Neutral pH (4.5–7.0) Stable; recommended pH range for reconstitution and working solutions
Acidic pH (<4.0) May promote aggregation of the C20 fatty diacid linker; avoid acidic buffers
Alkaline pH (>8.0) Risk of deamidation and C20 linker hydrolysis over extended incubation
Temperature Stress C20 eicosanedioic acid linker is hydrophobic; precipitation possible with temperature fluctuations. Gentle agitation recommended during reconstitution
Reconstituted Solution 24 h at 2–8°C; aliquot and freeze at −20°C for ≤30 days

Frequently Asked Questions

Q: What purity specifications apply to retatrutide?

≥99.0% by HPLC at 214 nm with ESI-MS mass identity confirmation (±1.0 Da). Comprehensive QC includes peptide content (≥80.0%), water content (≤5.0%), counterion analysis (acetate form, ≤1.0% TFA), and endotoxin testing (≤1.0 EU/mg). The intact C20 fatty diacid conjugate and full 39-aa sequence are confirmed in every batch-specific COA.

Q: How should retatrutide be stored after reconstitution?

Reconstituted retatrutide is stable for 24 hours at 2–8°C. For longer storage, aliquot into single-use portions and freeze at −20°C (stable ≤30 days). May require pH adjustment for complete dissolution. The C20 fatty acid linker is hydrophobic — gentle agitation, not vortexing, during reconstitution. Avoid repeated freeze-thaw cycles. Standard GLP-1 receptor agonist family storage conditions apply.

Source & Purchase

For researchers requiring RETATRUTIDE with full analytical documentation including HPLC and LC-MS traces, visit the PeptideSourceHub product page for bulk pricing and specifications.

Purchase RETATRUTIDE with COA →

Product Link
Tirzepatide (Dual GIP/GLP-1) tirzepatide.md — First-in-class dual GIPR/GLP-1R agonist
Semaglutide (GLP-1 RA) semaglutide.md — Selective GLP-1 receptor agonist with C18 linker
Cagrilintide (Amylin Analog) cagrilintide.md — Long-acting amylin receptor agonist
AOD-9604 (hGH Fragment) aod-9604.md — Lipolytic hGH fragment 177-191