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Tirzepatide

Identification

Property Value
Molecular Formula C₂₂₅H₃₄₈N₄₈O₆₈
Molecular Weight ~4,813.5 Da
Amino Acid Count 39
Appearance White to off-white lyophilized powder
Solubility Soluble in aqueous buffers; reconstitution may require gentle agitation due to lipophilic C20 fatty diacid linker
Receptor Targets GIPR / GLP-1R (dual agonist)

Structural & Pharmacological Profile

Tirzepatide is a first-in-class dual GIP and GLP-1 receptor agonist. Its design incorporates an imbalanced agonist profile, with greater potency at the GIP receptor relative to the GLP-1 receptor. The C20 fatty diacid moiety conjugated via a linker to Lys²⁰ provides extended pharmacokinetics through albumin binding.

Key Structural Features

Feature Detail
Peptide Backbone 39-amino acid linear peptide based on GIP sequence with GLP-1 activity-optimizing substitutions
Fatty Acid Moiety C20 eicosanedioic acid (icosanedioic acid)
Linker Chemistry gamma-Glu-2xOEG (gamma-glutamyl-bis-ethylene glycol) spacer to Lys²⁰
DPP-4 Resistance Engineered sequence prevents rapid enzymatic cleavage
Half-Life ~5 days in preclinical models

Comparator Analysis

Parameter Semaglutide Tirzepatide Retatrutide
Receptor Target GLP-1R (selective) GIPR / GLP-1R (dual) GIPR / GLP-1R / GCGR (triple)
Molecular Weight ~4,113.6 Da ~4,813.5 Da ~4,845.5 Da
Amino Acid Count 31 39 39
Clinical BW Reduction ~14.9% (STEP 1, 68 wk) ~22.5% (SURMOUNT-1, 72 wk) ~24.2% (Ph2, 48 wk)
Synthesis Complexity High Very High Complex
Half-Life ~7 days ~5 days ~6 days
Fatty Acid Linker C18 fatty diacid C20 fatty diacid C20 fatty diacid
Receptor Bias GLP-1R only GIPR > GLP-1R Balanced triple agonism

Clinical data cited from published trial results in peer-reviewed literature. Comparative efficacy figures are derived from distinct trial populations and protocols; direct cross-trial comparisons should account for differences in study design, duration, and population characteristics.

Research Applications

Research Domain Description
Metabolic Regulation Investigation of dual incretin receptor agonism on glucose-dependent insulin secretion, glucagon suppression, and insulin sensitivity
Body Weight & Adiposity Preclinical and clinical studies demonstrating substantial body weight reduction via combined central and peripheral mechanisms
Cardiovascular Outcomes HFpEF outcomes; blood pressure and lipid profile improvements
NASH / MASLD Significant histological improvement in MASH resolution without worsening of fibrosis
Renal Outcomes Reduction in albuminuria and composite renal endpoints in type 2 diabetes
Obstructive Sleep Apnea Investigated as adjunct therapy; weight-loss-mediated improvement in AHI

Quality Specifications

Parameter Specification Method
Purity (HPLC) ≥99.0% RP-HPLC, C18 column, 214 nm
Mass Identity MW ±1.0 Da ESI-MS
Water Content ≤5.0% Karl Fischer titration
Peptide Content ≥80.0% Amino acid analysis
Counterion Acetate form (≤1.0% TFA) Ion chromatography
Endotoxin ≤1.0 EU/mg LAL kinetic chromogenic
Residual Solvents ≤ ICH Q3C limits Headspace GC
pH (1 mg/mL) 5.0–7.5 Potentiometric

Available Configurations

Format Size Vials per Kit
Standard Research Kit 5 mg × 10 vials 10
Extended Research Kit 10 mg × 10 vials 10
Custom Configuration Bulk/custom sizes Per project

Storage & Stability

Condition Requirement
Short-term Storage 2–8°C, lyophilized form
Long-term Storage −20°C to −80°C
Light Protection Store in amber vials or opaque containers
Reconstituted 24 h at 2–8°C; −20°C for longer-term aliquots
Shipping Cold chain (2–8°C) recommended; ambient acceptable ≤7 days

Documentation

  • COA per batch: HPLC purity chromatogram, MS spectrum, quantitative data
  • MSDS per shipment
  • C20 Linker Integrity Report included with bulk orders

Special Notes

  • FOR LABORATORY RESEARCH USE ONLY.
  • Tirzepatide synthesis complexity is rated Very High due to the 39-amino acid sequence length, C20 fatty acid conjugation, and multiple non-proteinogenic modifications. Batch-to-batch consistency is assured through rigorous HPLC-MS characterization.
  • Dual agonism research protocols should consider receptor occupancy and signaling bias when designing comparative experiments.

Key Research References

Reference PMID Key Finding
Coskun T et al. "LY3298176, a novel dual GIP and GLP-1 receptor agonist for the treatment of type 2 diabetes mellitus: From discovery to clinical proof of concept." Mol Metab. 2018;18:3–14. 30473097 Preclinical characterization of tirzepatide demonstrating dual GIPR/GLP-1R agonism with imbalanced activity favoring GIPR; superior glycemic and weight reduction vs selective GLP-1R agonism
Jastreboff AM et al. "Tirzepatide once weekly for the treatment of obesity." N Engl J Med. 2022;387(3):205–216. 35658024 SURMOUNT-1 pivotal trial: tirzepatide produced up to 22.5% body weight reduction at 72 weeks in participants with obesity
Frias JP et al. "Tirzepatide versus semaglutide once weekly in patients with type 2 diabetes." N Engl J Med. 2021;385(6):503–515. 34170647 SURPASS-2: head-to-head comparison demonstrating superior HbA1c and body weight reductions vs semaglutide 1.0 mg

Stability & Storage

Condition Degradation Profile
Lyophilized Storage Standard lyophilized peptide stability; desiccated, temperature-controlled storage. 24 months at 2–8°C, 36 months at −20°C
Neutral pH (5.0–7.5) Stable; recommended for reconstitution and working solutions
Acidic pH (<4.0) May promote aggregation of the hydrophobic C20 linker; avoid acidic buffers
Alkaline pH (>8.0) Risk of deamidation and C20 linker hydrolysis over extended incubation
Temperature Stress C20 fatty diacid linker is hydrophobic; aggregation/precipitation possible with temperature fluctuations. Gentle agitation during reconstitution recommended
Reconstituted Solution 24 h at 2–8°C; aliquot and freeze at −20°C for ≤30 days. Avoid repeated freeze-thaw

Frequently Asked Questions

Q: What purity specifications apply to tirzepatide?

≥99.0% by HPLC at 214 nm with ESI-MS mass identity confirmation (±1.0 Da). Comprehensive QC includes peptide content (≥80.0%), water content (≤5.0%), TFA content (≤1.0%) via ion chromatography, and linker integrity verification. The C20 fatty diacid conjugate is confirmed intact in every batch-specific COA.

Q: How should tirzepatide be stored after reconstitution?

Reconstituted tirzepatide is stable for 24 hours at 2–8°C. For longer storage, aliquot into single-use sterile vials and freeze at −20°C (stable ≤30 days). The C20 fatty diacid linker is highly hydrophobic — gentle agitation may be required during reconstitution. Never vortex. Avoid strongly acidic (pH < 4) or alkaline (pH > 8) buffers. Do not subject to repeated freeze-thaw cycles.

Source & Purchase

For researchers requiring TIRZEPATIDE with full analytical documentation including HPLC and LC-MS traces, visit the PeptideSourceHub product page for bulk pricing and specifications.

Purchase TIRZEPATIDE with COA →

Product Link
Semaglutide (GLP-1 RA) semaglutide.md — Selective GLP-1 receptor agonist
Retatrutide (Triple Agonist) retatrutide.md — Triple GIPR/GLP-1R/GCGR agonist
Cagrilintide (Amylin Analog) cagrilintide.md — Long-acting amylin receptor agonist
AOD-9604 (hGH Fragment) aod-9604.md — Lipolytic hGH fragment 177-191